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Rough times:

0:03 - 0:09 = Powerball
0:09 - 0:16 = LE456
0:16 - 0:22 = Powerball
0:22 - 0:29 = LE456

The main differences I hear are:

1) The LE456 has slightly shorter decay time
2) The Powerball has a bit more mids
3) The LE456 has a bit more treble than the real Powerball

These are of course when comparing to using the exact same settings on both. I'm sure with just a little bit of tweaking they'll sound identical. You can especially hear the decay difference on the first high note of the riff. Both use the same (quad) DI tracks, so it's not a difference in playing.

Oh and the settings (0 - 10):

Lo Lead
Gain 3,5
Bass 3
Mid-Focused 10
Treble 6,5 (real), 4,5 (sim)
Bottom off
Presence & Depth Punch 5 (real), Contour 5 (sim)